| The Formation of Urinary Calculi [or Kidney stones (renal lithiasis, nephrolithiasis)]
is a serious disease among Iran’s population, inasmuch as renal stone prevalence rate
is annually about 145 cases per 100,000 men and women. In this study, the mineralogy
and elemental composition of urinary stones were studied in East Azerbaijan province,
located in northwest of Iran. X-ray diffraction (XRD), X-ray fluorescence (XRF)
and atomic absorption spectroscopy (AAS) analyses were used to investigate the
mineralogy of different types of Urinary Calculi. The results showed that the collected
Urinary Calculi samples can be divided into four groups, based on their mineralogical
aspect: mono-hydrated calcium oxalate, di-hydrated calcium oxalate, uric acid and
urate/calcium oxalate/cystine, in which whewellite and uricite were the most abundant
mineral phases. The oxalate stone types were characterized by the high concentrations
of zinc, phosphorus and magnesium. Common minerals in the studied renal stones
indicated that calcium oxalate urinary stones have a similar prevalence ratio as in
Middle East countries. However, urate compounds were significantly higher in Iran
compared to other countries; The niahite mineral was not found in studied samples.
In the cities having very hard and hard drinking water, uric acid and oxalate type stone
were the main phases in East Azerbaijan province with Mediterranean climate, urate
urinary stones were dominant. XRF results indicated that the frequency of Ca was from
0.11 to 25.63%, which has the highest concentration among other elements. The strong
positive correlation between Ca and P indicated that calcium tends to be participated in
the structure of phosphorus-bearing urinary stones. |