Predicting the solubility, thermodynamic properties and preferential solvation of sulfamethazine in {acetonitrile + water} mixtures using a minimum number of experimental data points
Predicting the solubility, thermodynamic properties and preferential solvation of sulfamethazine in {acetonitrile + water} mixtures using a minimum number of experimental data points
نویسندگان: مریم خوب نسب جعفری , ابوالقاسم جویبان
کلمات کلیدی: Solubility prediction;
co-solvency models;
Jouyban-Acree model;
Jouyban-Acree-van’t Hoff
model; apparent
thermodynamic properties;
preferential solvation
نشریه: 27374 , , , 2020
| نویسنده ثبت کننده مقاله |
ابوالقاسم جویبان |
| مرحله جاری مقاله |
تایید نهایی |
| دانشکده/مرکز مربوطه |
مرکز تحقیقات آنالیز دارویی |
| کد مقاله |
73880 |
| عنوان فارسی مقاله |
Predicting the solubility, thermodynamic properties and preferential solvation of sulfamethazine in {acetonitrile + water} mixtures using a minimum number of experimental data points |
| عنوان لاتین مقاله |
Predicting the solubility, thermodynamic properties and preferential solvation of sulfamethazine in {acetonitrile + water} mixtures using a minimum number of experimental data points |
| ناشر |
5 |
| آیا مقاله از طرح تحقیقاتی و یا منتورشیپ استخراج شده است؟ |
بلی |
| عنوان نشریه (خارج از لیست فوق) |
|
| نوع مقاله |
Original Article |
| نحوه ایندکس شدن مقاله |
ایندکس شده سطح یک – ISI - Web of Science |
| آدرس لینک مقاله/ همایش در شبکه اینترنت |
|
| The all experimental solubility data of sulphamethazine in {acetonitrile (1)
+ water (2)} binary solvent mixtures at temperature range from (278.15 to
323.15) K have been carefully reanalysed. Then, a minimum number of
experimental solubility data has been chosen to predict the solubility data
at all possible solvent compositions and temperatures using interpolation
technique. The predicted data was compared with the experimental data
employing the average absolute percentage deviation (AAPD) as an accuracy
criterion. The preferential solvation analyses based on the inverse
Kirkwood-Buff integrals and also apparent thermodynamic properties
were conducted employing the simulated data and the obtained results
were compared with those obtained employing all data points. Gibbs
energy and preferential solvation follow similar trends but enthalpy and
entropy of dissolution exhibit significant differences. |
| نام فایل |
تاریخ درج فایل |
اندازه فایل |
دانلود |
| Phys Chem Liq in press.pdf | 1399/07/14 | 1954033 | دانلود |
