Modeling the Rheological Behavior of Chemically Interesterified Blends of Palm Stearin/Canola Oil as a Function of Physicochemical Properties

Modeling the Rheological Behavior of Chemically Interesterified Blends of Palm Stearin/Canola Oil as a Function of Physicochemical Properties


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نویسندگان: مهناز طبیبی اذر

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نشریه: 0 , 11 , 96 , 2019

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نویسنده ثبت کننده مقاله مهناز طبیبی اذر
مرحله جاری مقاله تایید نهایی
دانشکده/مرکز مربوطه دانشکده تغذیه
کد مقاله 70810
عنوان فارسی مقاله Modeling the Rheological Behavior of Chemically Interesterified Blends of Palm Stearin/Canola Oil as a Function of Physicochemical Properties
عنوان لاتین مقاله Modeling the Rheological Behavior of Chemically Interesterified Blends of Palm Stearin/Canola Oil as a Function of Physicochemical Properties
ناشر 4
آیا مقاله از طرح تحقیقاتی و یا منتورشیپ استخراج شده است؟ خیر
عنوان نشریه (خارج از لیست فوق) JAOCS Journal of the American Oil Chemists' Society
نوع مقاله Original Article
نحوه ایندکس شدن مقاله ایندکس شده سطح یک – ISI - Web of Science
آدرس لینک مقاله/ همایش در شبکه اینترنت

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The main aim of the current study was to model the rheological and textural properties of chemically interesterified palm stearin (PS)/canola oil (CO) blends as a function of saturated fatty acids (SFA), solid fat content (SFC), and temperature. The results and proposed models in this study can be used in design and development of new fat products by trying to limit the need for instrumental methods. To describe and predict how the viscoelastic properties and firmness of the blends change with SFA content, several models have been proposed. The firmness curves of fat samples were described as a function of (SFA, Firmnessf(SFA), Rsqr = 0.94, and mean absolute error (MAE) = 1009.00 g) and (SFC20, Firmnessf(SFC20), Rsqr = 0.98, and MAE = 750.80 g) using a one-variable Quadratic model. In the next step, a two-variable Quadratic function for expression of firmness as a function of both SFA content and SFC20 with high goodness of fit and low error (Rsqr = 1.00 and MAE = 0.00) was developed. The G0 modulus as a function of temperature (G0 f(T)) and SFC (G’f(SFC)) curves was S-shaped and the three Sigmoidal functions (Logistic, Gompertz, and Sigmoid models) were well able to describe their properties. However, the Logistic models described the G0 f(T) (Rsqr>0.99 and MAE < 7838.00 Pa) and G0 f(SFC) (Rsqr>0.94 and MAE < 20,802.00 Pa) curves in the best way. Finally, a two-variable Logistic model considering both temperature and SFC as variables was developed and fitted on the experimental data with Rsqr of 0.97 and MAE of 85,367.56 Pa. The validation of the proposed models shows their efficiency and ability for prediction of rheological and textural values of various interestrified blends.

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مهناز طبیبی اذرسوم

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