Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1) + water (2)} mixtures
Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1) + water (2)} mixtures
نویسندگان: ابوالقاسم جویبان
کلمات کلیدی: Triclocarban, Solubility, {1,4-dioxane + water} mixtures, Jouyban-Acree model, Thermodynamic quantities
نشریه: 18106 , 23 , 271 , 2018
| نویسنده ثبت کننده مقاله |
ابوالقاسم جویبان |
| مرحله جاری مقاله |
تایید نهایی |
| دانشکده/مرکز مربوطه |
مرکز تحقیقات آنالیز دارویی |
| کد مقاله |
68880 |
| عنوان فارسی مقاله |
Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1) + water (2)} mixtures |
| عنوان لاتین مقاله |
Enthalpy-entropy compensation analysis of the triclocarban dissolution process in some {1,4-dioxane (1) + water (2)} mixtures |
| ناشر |
7 |
| آیا مقاله از طرح تحقیقاتی و یا منتورشیپ استخراج شده است؟ |
خیر |
| عنوان نشریه (خارج از لیست فوق) |
|
| نوع مقاله |
Original Article |
| نحوه ایندکس شدن مقاله |
ایندکس شده سطح یک – ISI - Web of Science |
| آدرس لینک مقاله/ همایش در شبکه اینترنت |
|
| The equilibrium solubility of triclocarban in {1,4-dioxane (1) + water (2)} mixtures at 293.15 K to 313.15 K was
reported. Mole fraction solubility increases continuously from neat water to neat 1,4-dioxane at all temperatures.
Solubility behavior was adequately correlated by means of a number of cosolvency models including the
Jouyban-Acree model. Based on the Gibbs and van't Hoff equations the respective apparent thermodynamic
quantities of dissolution were calculated. Non-linear enthalpy-entropy compensation analysis is observed indicating different dissolution mechanism with the variation in mixtures composition |
| نام فایل |
تاریخ درج فایل |
اندازه فایل |
دانلود |
| 1-s2.0-S0167732218318312-main.pdf | 1398/06/21 | 909718 | دانلود |
