Synthesis and characterization of electroactive bottlebrush nano‑copolymers based on polystyrene and polyaniline as side chains and poly(3‑(2‑hydroxyethyl)thiophene) as backbone

Synthesis and characterization of electroactive bottlebrush nano‑copolymers based on polystyrene and polyaniline as side chains and poly(3‑(2‑hydroxyethyl)thiophene) as backbone


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صفحه نخست سامانه
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دانشگاه علوم پزشکی تبریز
دانشگاه علوم پزشکی تبریز

نویسندگان: رعنا سروری

کلمات کلیدی: Bottlebrush · Graft · ATRP · PSt · PANI

نشریه: 27910 , 3707-3724 , 77 , 2019

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نویسنده ثبت کننده مقاله رعنا سروری
مرحله جاری مقاله تایید نهایی
دانشکده/مرکز مربوطه مرکز سلولهای بنیادی
کد مقاله 68858
عنوان فارسی مقاله Synthesis and characterization of electroactive bottlebrush nano‑copolymers based on polystyrene and polyaniline as side chains and poly(3‑(2‑hydroxyethyl)thiophene) as backbone
عنوان لاتین مقاله Synthesis and characterization of electroactive bottlebrush nano‑copolymers based on polystyrene and polyaniline as side chains and poly(3‑(2‑hydroxyethyl)thiophene) as backbone
ناشر 4
آیا مقاله از طرح تحقیقاتی و یا منتورشیپ استخراج شده است؟ خیر
عنوان نشریه (خارج از لیست فوق)
نوع مقاله Original Article
نحوه ایندکس شدن مقاله ایندکس شده سطح یک – ISI - Web of Science
آدرس لینک مقاله/ همایش در شبکه اینترنت

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Electroactive bottlebrush copolymers were synthesized via grafting of polystyrene (PSt) and polyaniline (PANI) from poly(3-(2-hydroxyethyl)thiophene) backbones by atom transfer radical polymerization (ATRP) and chemical oxidation polymeriza tion. The bromoesters were attached to the polymer chains to afford the proper mac roinitiators for ATRP of PSt branches. Likewise, some other polymer chains were functionalized with antranilic acid for chemical oxidation polymerization of PANI. Electroactivity behaviors of the synthesized bottlebrushes were approved by the cyclic voltammetry, and their conductivities were determined using the four-probe technique. Thanks to the electrical conductivity and thermal stability, the synthe sized bottlebrushes can be appropriate candidates for being used in various systems such as organic solar cells.

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رعنا سروریسوم

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