ENHANCEMENT OF 4-NITROPHENOL OZONATION IN WATER BY NANO ZnO CATALYST

ENHANCEMENT OF 4-NITROPHENOL OZONATION IN WATER BY NANO ZnO CATALYST


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نویسندگان: سیاوش دستمالچی

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نشریه: 0 , 4 , 8 , 2011

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نویسنده ثبت کننده مقاله سیاوش دستمالچی
مرحله جاری مقاله تایید نهایی
دانشکده/مرکز مربوطه مرکز تحقیقات بیوتکنولوژی(زیست فناوری)
کد مقاله 59493
عنوان فارسی مقاله ENHANCEMENT OF 4-NITROPHENOL OZONATION IN WATER BY NANO ZnO CATALYST
عنوان لاتین مقاله ENHANCEMENT OF 4-NITROPHENOL OZONATION IN WATER BY NANO ZnO CATALYST
ناشر 4
آیا مقاله از طرح تحقیقاتی و یا منتورشیپ استخراج شده است؟ بلی
عنوان نشریه (خارج از لیست فوق) Iran Journal Health sci Eng
نوع مقاله Original Article
نحوه ایندکس شدن مقاله ایندکس شده سطح یک – ISI - Web of Science
آدرس لینک مقاله/ همایش در شبکه اینترنت http://search.proquest.com/docview/920399766/fulltextPDF/CBA606563F584263PQ/1?accountid=41307

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The removal of 4-nitrophenol (4NP) from aqueous solution by ozone combined with nano-ZnO was investigated in a laboratory-scale reactor in which pH of solution, ZnO dosage and initial 4-nitrophenol concentration were considered as variables. The degradation of 4-nitrophenol was determined using UV-Vis and HPLC methods. Interestingly, the degradation of 4-nitrophenol was high under acidic condition where the degradation was about 93% at initial phenol solution pH=3. It was due to aggregation of nano-ZnO particles above pH=6.5. This result was different from the case of ozonation alone, in which higher pH had positive effect on the degradation of 4-nitrophenol due to the formation of hydroxyl radical. As expected, degradation efficiency increased by increasing the nano ZnO dosage and initial 4-nitrophenol concentration. It was found that the nanosized ZnO enhanced the degradation of ozone and the catalytic ozonation enhanced the degradation of 4-nitrophenol on the surface of the nanosized ZnO. In addition, the degree of degradation was also determined indirectly through Total Organic Carbon (TOC) of the samples. Carbon mineralization of 4-nitrophenol was obtained as 13.68% and 60.34% during ozonation and nano-ZnO catalytic ozonation, respectively, after 30 min reaction, proving that combined ozonation and nano-ZnO for reduction of TOC is more efficient. Also a high degree of nitrogen mineralization during catalytic ozonation was achieved at pH= 3 (7.61mg/L).

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