Degradation of trace aqueous 4-chloro-2-nitrophenol occurring in pharmaceutical industrial wastewater by ozone

Degradation of trace aqueous 4-chloro-2-nitrophenol occurring in pharmaceutical industrial wastewater by ozone


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دانشگاه علوم پزشکی تبریز
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نویسندگان: سیاوش دستمالچی

کلمات کلیدی: Chemical oxygen demand; Degradation; Kinetic; Mineralization; Total organic carbon

نشریه: 55244 , 2 , 7 , 2010

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نویسنده ثبت کننده مقاله سیاوش دستمالچی
مرحله جاری مقاله تایید نهایی
دانشکده/مرکز مربوطه مرکز تحقیقات بیوتکنولوژی(زیست فناوری)
کد مقاله 59371
عنوان فارسی مقاله Degradation of trace aqueous 4-chloro-2-nitrophenol occurring in pharmaceutical industrial wastewater by ozone
عنوان لاتین مقاله Degradation of trace aqueous 4-chloro-2-nitrophenol occurring in pharmaceutical industrial wastewater by ozone
ناشر 6
آیا مقاله از طرح تحقیقاتی و یا منتورشیپ استخراج شده است؟ بلی
عنوان نشریه (خارج از لیست فوق)
نوع مقاله Original Article
نحوه ایندکس شدن مقاله ایندکس شده سطح یک – ISI - Web of Science
آدرس لینک مقاله/ همایش در شبکه اینترنت http://link.springer.com/article/10.1007/BF03326147

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Degradation of 4-chloro-2-nitro phenol by ozonation in aqueous solution was studied in a semi batch reactor under constant ozone dosage and variable pH conditions. The effectiveness of the process was estimated based on the degree of conversion of 4-chloro-2-nitro phenol. It was observed that ozonation is more effective at alkaline reaction of medium than other conditions. The degree of conversion achieved (at the first 5 minutes of the process)at pH 9 was 99.64% compared to 99.03% and 77.35% at pH 7 and 3, respectively. Another parameter used to quantify the 4chloro-2-nitrophenol during ozonation was the pseudo first order rate constant k [min ]. Results showed that the rate constant of the process was approximately much higher at the alkaline pH compared to acidic ones. A considerable improvement in chemical oxygen demand removal was observed at pH above 7. At pH 9, the reduction in chemical oxygen demand at the end of the process reached 56.9 %. The degree of organically bounded nitrogen conversion to nitrate was higher at pH 3. Of the total organic carbon reduction, 15.89 % was observed at pH 9. The 4-chloro-2-nitro phenol degradation intermediate products were analyzed by mass- spectrometry. The main intermediate product was chlorophenol.

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سیاوش دستمالچیپنجم

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